A Discussion on the Mass Spectrometric Cleavage of 1,1—Dichloro—2—ethyloxy—2—Arylolefins
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Graphical Abstract
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Abstract
A study on the mass spectrometric cleavage of 1, 1—dichloro—2—ethyloxy—2—AryIolefins by metastable ions and precise mass measurement is reported. The mechanism via McLafferty rearrangement and then 1, 3—hydrogen shift is suggested.
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