Characteristics and Identification of Saturated Hydrocarbons by Comprehensive Two-Dimensional Gas Chromatography Coupled to Time-of-Flight Mass Spectrometry

WANG Hui-tong; WENG Na; ZHANG Shui-chang; CHEN Jian-ping; WEI Cai-yun

Journal of Chinese Mass Spectrometry Society > 2010 > 31(1): 18-27.

WANG Hui-tong, WENG Na, ZHANG Shui-chang, CHEN Jian-ping, WEI Cai-yun. Characteristics and Identification of Saturated Hydrocarbons by Comprehensive Two-Dimensional Gas Chromatography Coupled to Time-of-Flight Mass Spectrometry[J]. Journal of Chinese Mass Spectrometry Society, 2010, 31(1): 18-27.

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Characteristics and Identification of Saturated Hydrocarbons by Comprehensive Two-Dimensional Gas Chromatography Coupled to Time-of-Flight Mass Spectrometry

1.
Petroleum Geology Research and Laboratory Center, Research Institute of Petroleum Exploration and Development, CNPC, Beijing 100083, China
2.
The Key Laboratory of Petroleum Geochemistry, CNPC, Beijing 100083, China
3.
State Key Laboratory of Enhanced Oil Recovery, Beijing 100083, China

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Received Date: December 31, 1899
Revised Date: December 31, 1899

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Abstract

Abstract

A method for the analysis of saturated hydrocarbons in crude oil was established by comprehensive two-dimensional gas chromatography coupled to time-of-flight mass spectrometer(GC×GC/TOFMS). All compounds were identified according to their family characteristics and each spectrum. Alkanes， cyclic alkanes， bicyclic alkanes， adamantanes， diamantanes， terpanes， steranes and hopanes are separated into easily recognizable bands in the GC×GC chromatogram. The characteristics of terpanes， hopanes and adamantanes’ contour chromatogram are defined. C₃₁—C₃₅tricyclic terpanes were often neglected in the past. Provide petroleum geological experiment workers reference to carry out their work on GC×GC/TOFMS. Compare with the GC/MS, GC×GC/TOFMS has higher sensitivity and bigger peak capacity, which is more suitable for the analysis of complex mixture systems. It will be a helpful tool in the petroleum geological experiment.

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Characteristics and Identification of Saturated Hydrocarbons by Comprehensive Two-Dimensional Gas Chromatography Coupled to Time-of-Flight Mass Spectrometry

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