Advanced Search
HUANG Yi, LI Guo-ao, RAO Zhu, JI Hong-bing. Determination of Volatile Organic Compounds in City Groundwater by GC/MS with Purge and Trap Sampling[J]. Journal of Chinese Mass Spectrometry Society, 2012, 33(5): 301-307.
Citation: HUANG Yi, LI Guo-ao, RAO Zhu, JI Hong-bing. Determination of Volatile Organic Compounds in City Groundwater by GC/MS with Purge and Trap Sampling[J]. Journal of Chinese Mass Spectrometry Society, 2012, 33(5): 301-307.
shu

Determination of Volatile Organic Compounds in City Groundwater by GC/MS with Purge and Trap Sampling

  • 1.

    National Research Center for Geoanalysis, Beijing 100037, China

  • 2.

    Capital Normal University, Beijing 100048, China

More Information
  • Received Date: December 31, 1899
  • Revised Date: December 31, 1899
    Graphical Abstract
    • Abstract
  • A method was developed for simultaneous detection of 34 volatile organic compounds (VOCs) such as hexachlorobutadiene, pentachloroethane, hexachloroethane, epichlorohydrin in groundwater by gas chromatography-mass spectrometry（GC/MS） with purge and trap sampling. Isotope-labeled toluene-d8 and 1,2-dichlorobenzene-d4 were used as the internal standard for the quantitative analysis. The detection limits the target compounds are 0.01—0.09 μg/L. The recovery rates are 97.0%—107% with precision of 1.04%—7.6% (RSD, n=7). The method provides the advantages of lower detection limits, good precision， and which is suitable for the determination of trace VOCs in groundwater.
    • FullText(HTML)
    • References (20)
  • [1]
    刘菲，王苏明，陈鸿汉.欧美地下水有机污染调查评价进展[J].地质通报，2010,29(6):907-917.
    [2]
    张新钰，辛宝东，王晓红，等.我国地下水污染研究进展[J].地球与环境，2011,39(3):415-466.
    [3]
    王昭，王慧珍，石建省，等. 地下水有机污染研究进展[J]. 勘查科学技术，2008，35(6):39-42.
    [4]
    吕书君.我国地下水污染分析[J].地下水，2009,31(1):1-5.
    [5]
    赵勇胜，曹玉清.地下水的有机污染[J].工程勘察，1995,(1):28-31.
    [6]
    高存荣, 王俊桃.我国69 个城市地下水有机污染特征研究[J].地球学报，2011,32(5):581-591.
    [7]
    刘征涛. 环境安全与健康[M]. 北京：化学工业出版社，2005：212-223.
    [8]
    饶竹，李松，吴淑琪，等. 地质调查中有机物分析方法研究及应用[J]. 地球学报，2009，30(3):291-300.
    [9]
    饶竹. 环境有机污染物检测技术及其应用[J]. 地质学报, 2011，85（11）：1 948-1 962.
    [10]
    U.S. Environmental Protection Agency, Toxicological Review of Hexachloroethane. EPA/635/R-09/007A, 2010:5-16.
    [11]
    中华人民共和国卫生部中国国家标准化管理委员会.GB 5749—2006，生活饮用水卫生标准[S].北京：中国标准出版社，2007.
    [12]
    国家环保总局. 水和废水监测分析方法[M]. 4版，北京：中国环境科学出版社，2002：550-565.
    [13]
    中国地质调查局. 地下水污染调查评价规范(1:50000-1:250000). 2006.
    [14]
    文冬光，林良俊，孙继朝，等. 区域性地下水有机污染调查与评价方法[J]. 中国地质，2008，35(5):814-819.
    [15]
    崔亚伟，陈金发. 地下水有机污染物监测技术的研究现状[J]. 地下水，2009，31(2):23-26.
    [16]
    US EPA Method 5030C, Purge and trap for aqueous samples[S].
    [17]
    US EPA Method 5035, Closed system purge and tap and extraction for volatile organics in soil and waste Samples [S].
    [18]
    US EPA Method 8260B,Volatile organic compounds by gas chromatography/mass spectrometry (GC/MS)[S].
    [19]
    US EPA Method 524, Measurement of purgeable organic compounds in water by capillary column gas chromatography/mass spectrometry [S].
    [20]
    黄毅，饶竹.吹扫捕集气相色谱-质谱法测定地下水调查样品中挥发性有机污染物[J]. 岩矿测试，2009，25(1):15-20.
    • Related Articles

  • Related Articles

    [1]LU Xin-xin, ZHANG Shuo, XU Kai, QIU Jun-wei, ZHU Hui-jun, CHEN Yu-lin, LI Xiao-xu. Rapid On-site Detection of Microleakage of Lithium Battery Electrolytes by Vacuum-Assisted Volatilization-Portable Gas Chromatography-Mass Spectrometry[J]. Journal of Chinese Mass Spectrometry Society, 2025, 46(2): 149-159. DOI: 10.7538/zpxb.2024.0126
    [2]LUO Qian, QU Guo-run, LYU Ji-yang, SUN Wei, ZHANG Wei, ZHU Xin-de, SHI Jian-xin. Determination of Wax Components on Lotus Leaves by GC-MS[J]. Journal of Chinese Mass Spectrometry Society, 2021, 42(1): 56-64. DOI: 10.7538/zpxb.2019.0134
    [3]LI Xin, WANG Yu, XING Li-li, ZHOU Zhong-yue, YANG Jiu-zhong, QI Fei, PAN Yang. Pyrolysis Study of Flame Retarded Polyurethane with On-line Photoionization Mass Spectrometry and GC/MS[J]. Journal of Chinese Mass Spectrometry Society, 2016, 37(2): 97-105. DOI: 10.7538/zpxb.youxian.2016.0006
    [4]CHEN Xiao-shui, HOU Hong-wei, BIAN Zhao-yang, TANG Gang-ling, HU Qing-yuan. Research Progress on Application of GC-MS/MS[J]. Journal of Chinese Mass Spectrometry Society, 2013, 34(5): 308-320. DOI: 10.7538/zpxb.2013.34.05.0308
    [5]WANG Yu, LIU Xue-feng, LIU Cong, REN Min. Determining Volatile Compounds in Indocalamus bashanensis Leaves by Purge-and-Trap GC/MS[J]. Journal of Chinese Mass Spectrometry Society, 2012, 33(2): 104-108.
    [6]GAO Yan-yan, ZHAO Xue-hong, HUANG Chao, WANG Yan. Numerical Analysis on the Gas Density in the Ion Source of GC/MS[J]. Journal of Chinese Mass Spectrometry Society, 2010, 31(4): 202-207.
    [7]SUN Yu-mei, WANG Yu-fan, LIU Fei, SUN Jing, Lü Guo, GAO Wen-qian. Determining Semi-volatile Organic Substances of Groundwater through Liquid-liquid Extraction-C18 Membrane Disk Extraction-GS/MS[J]. Journal of Chinese Mass Spectrometry Society, 2006, 27(3): 140-147.
    [8]Determination of Tetramine in Blood by Gas Chromatography-Mass Spectrometry[J]. Journal of Chinese Mass Spectrometry Society, 2004, 25(4): 253-253.
    [9]Pyrolysis Research on Cigarette at Different Temperatures by GC/MS[J]. Journal of Chinese Mass Spectrometry Society, 2003, 24(1): 283-283.
    [10]Determination of PCBs in Fish Oil by GC/MS[J]. Journal of Chinese Mass Spectrometry Society, 2003, 24(1): 261-261.

Catalog

    Get Citation
    PDF
    XML
    Article views (711) PDF downloads (848) Cited by()
    Turn off MathJax
    Article Contents
    Abstract
    References
    Related Articles
    Links

    Website Copyright © 2023 Journal of Chinese Mass Spectrometry Society  京ICP备12043220号-2

    Address: Box 65, P.O. Box 275, Beijing    Postal Code: 102413     Tel:010-69357734     E-mail:jcmss401@163.com

    Supported by: Beijing Renhe Information Technology Co., Ltd.  Baidu Analytics

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return