若干金属簇(配)合物的质谱和碎片重组反应研究

  • 摘要: 质谱是结构化学研究工具,又是一种化学反应器,因此,它既可用于解释分子结构及其能量相关性,又可提供气相离子化学反应进行化学合成的一种有效手段,本文结合这两方面研究结果加以总结。

     

    Abstract: Mass Spectroscopic Studies and Recombination Reactions of Fragment Species of Some Metal Complexes and ClustersCat Yuanba; Dai Liang; Kang Beishang;Liu Qiutian; Lu Jiaxi(Fujian Institute of Research on the Structureof Matter, Chinese Academy of Science, andState Key Laboratory of Structural Chemistry,Fuzhou 350002, Fujian, China)Abstract:The mass spectrometry is both a tool for structural determination and a reactor ochemical synthesis in gas phase. Thus it offerds both informations of molecular structures and gas phase molecular-ion reactions. This paper summarizes the results on hottopics: (1)comparison of EI and FAB mass spectrometry and its correlation to clusteconversion for MoFe3S4L5 (L= S2CNC4H8) cuban-type clusters F (2) the recombinatiolreaction of fragment species of some metal complexes and clusters in mass spectrometry.Keywords: metal (complex) cluster compound, mass spectrometry, recombination reaction.

     

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