北京市大气颗粒物分级样品的铅同位素丰度比测量与来源研究

Lead Isotopic Measurements and Source Study for Size-Selective Aerosol Samples in Beijing

  • 摘要: 报道了北京市2004年夏、冬季分级采样样品的化学组成和铅同位素丰度比数据,并对铅来源进行了分析。采用电感耦合等离子体原子发射光谱(ICP-AES)和电感耦合等离子体质谱(ICP-MS)技术分析了24个无机元素浓度,同时用多接收器电感耦合等离子体质谱(MC-ICPMS)技术测定铅同位素丰度比。结果表明:细颗粒(PM2.5)中的铅含量明显高于粗颗粒(PM10~2.5),可吸入颗粒物(PM10)中80%以上的铅存在细颗粒。细颗粒的206Pb/207Pb比值处于1.140~1.156的范围;粗颗粒的206Pb/207Pb比值处于1.127~1.148的范围,总体上低于细颗粒。北京市大气铅来源复杂、多样,有2个或3个以上,主要来源除了燃煤排放还有涉铅有色冶金排放。基于前期工作积累的较多样品测量数据,燃煤排放的206Pb/207Pb代表性比值为1.163 3;涉铅有色冶金排放源的数据较少,初步判断处于1.11~1.15之间,中值为1.13。夏季、冬季细颗粒中燃煤源贡献率分别为0.51和0.59;涉铅有色冶金源的贡献率分别为0.49和0.41。北京市大气铅污染同时具有当地排放和区域性排放的贡献和特征。

     

    Abstract: Sizeselective aerosol samples, both fine fractions (PM2.5) and coarse fractions (PM10-2.5) were collected in 2004 in Beijing. There were 11 pairs in summer and 12 pairs in winter, respectively. For those samples 24 elements were determined using either ICP-AES or ICP-MS, and lead isotope abundances were measured using MC-ICP-MS. It was revealed that lead contents in fine fractions were substantially higher than those of coarse fractions. More than 80% of lead in PM10 samples was in the fine fractions. The 206Pb/207Pb ratios of fine fractions fell in the range of 1.140-1.156, while those of coarse fractions were lower, in the range of 1.127-1.148. There were three or more sources for aerosol lead in Beijing. The major sources include coal combustion and non-ferrous industrial emissions. Based on rich data accumulated so far, the representative 206Pb/207Pb ratio of coal combustion in Beijing is taken as 1.163 3. The data of non-ferrous industrial emissions have been limited and estimated in the range of 1.11-1.15, with 1.13 in the middle. Coal combustion emissions accounted for aerosol lead in Beijing a fraction of 0.51 and 0.59 in summer and winter, respectively; while lead related non-ferrous industrial emissions a fraction of 0.49 and 0.41, respectively. The aerosol lead in Beijing has contributions from both local emission sources and regional ones as well.

     

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