53Mn/55Mn实验室标准样品制备及加速器质谱测量

Preparation and Accelerator Mass Spectrometry Determination of 53Mn/55Mn Standard Reference Material

  • 摘要: 宇宙成因核素53Mn是一种非常理想的地质定年工具。近年来,随着加速器质谱(AMS)技术的不断发展,53Mn的高灵敏测量成为可能。本工作介绍了53Mn/55Mn的系列实验室标准样品的制备以及AMS测量,结果表明:53Mn/55Mn的测量值与标称值在误差范围内比较吻合且呈现良好的线性关系,中国原子能科学研究院的AMS系统对53Mn的测量灵敏度可以达到10-14

     

    Abstract: The cosmogenic isotope 53Mn is a very useful tool for geochronological dating. In recent years, with the development of AMS method, the high sensitivity mearsurment for 53Mn becomes advisable. High energy is required to remove the interference of 53Cr in the AMS measurement of 53Mn, only few AMS laboratories with high terminal voltage satisfy the condition in the world by now. In this paper, the preparation of 53Mn/55Mn laboratory standard’s series and the measurement with AMS method are introduced. In order to reduce the interference of 53Cr efficiently, ΔE-Q3D method was used in AMS measurement of 53Mn at China Institute of Atomic Energy (CIAE) based on the HI-13 Tandem Accelerator and the large Q3D magnetic mass spectrometer. The results show that the measured values are in good agreement with their nominal values and the linear relationship between them is excellent. The mearsurment sensitivity of 10-14 for 53Mn/55Mn ratio can be achieved by the AMS system at China Institute of Atomic Energy (CIAE).

     

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