锑、铕、铈、铒同位素丰度和原子量测量

  • 摘要: 用已知化学纯度的两种浓缩同位素通过化学计量,配制人工合成样品,用来测量质谱计系统误差校正系数,校正用该仪器测量的来自地球不同地域矿样和试剂样品中锑(Sb)、铕(Eu)、铈(Ce)、铒(Er)四种元素天然同位素丰度比,求出这些元素同位素丰度的真值。用该真值和已知的上述四元素核素质量,计算得原子量分别为121.7597(7)Sb、151.9644(9)Eu、140.1157(8)Ce、167.2591(9)Er

     

    Abstract: The Determination of Atomic Weights of Antimony,\=Europium,Cerium and ErbiumAuthor Zhao Motian,Wang Jun\=(National Research Center for Certified Reference Material,Beijing 100013,China)\=\=Received 1998-12-30\=\= Abstract \=\;Calibrated mass spectrometric measurements on highly enriched isotopes of Sb,Eu,Ce,Er in the form of oxides of well-defined purity were carried out using a thermal ionization mass spectrometer,yielding absolute isotopic compositions(see table 2)and atomic weights of antimony,europium,cerium and erbium as 121,7597(7)Sb,151,9644(4)Eu,140,1157(8)Ce and 167,2591(9)Er with an uncertainty given on the basis of 95% confidence limit.\=\=Key Words: atomic weight,absolute isotope abundance,antimony,europium,cerium,erbium

     

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