4,5-双烷氧基-1,2-二溴代苯及4,5-双卞氧基-1,2-二溴代苯质谱研究

  • 摘要: 本文对4,5双十一烷氧基-1,2-二溴代苯、4,5-双十四烷氧基-1,2-二溴代苯、4,5-双苄氧基-1,2-二溴代苯的电子轰击质谱进行了研究。发现前两个化合的质谱特征是烷基部分C-C键的断裂和烷氧基伴随着氢重排的O-C键断裂;而后者的质谱特征是苄氧基简单的O-C键断裂和重排碎片离子m/z181的产生

     

    Abstract: A Study on the Mass Spectrometry of 4,5Bisalkoxy1,2Dibromobenzenes and 4,5Bisbenzoxy1,2DibromobenzeneAuthor Lin Jimao(Department of Chemistry,Shandong University,Jinan 250100,China)Sun Yuanping(Jinan Medical Company,Jinan 250012,China)Received 19980801 Abstract Mass spectra of 4,5bisundecanoxy 1,2ibromobenzene,4,5bistetradecanoxy1,2dibromobenzene and 4,5bisbenzoxy1,2dibromobenzene were studied.The characteristics of the former two compounds are of CC bonds fragmentation of alkyl groups and OC bonds fragmentation accompanied by hydrogen migration of alkoxy groups.The characteristic of the latter is of simple CC bonds fragmentation and m/z 181 formation.Key Words: mass spectrometry,4,5bisalkoxy1,2dibromobenzene 4,5bisbenzoxy1,2dibromobenzene,fragmentation

     

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