植物激素甲氧肟/三甲基硅基衍生物的气相色谱-飞行时间质谱表征
Characterization of Phytohormones Methoxime and TMS Derivatives by Gas Chromatography Time-of-Flight Mass Spectrometry
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摘要: 采用气相色谱-飞行时间质谱(GC-TOF MS)研究4种植物激素甲氧肟/三甲基硅基(TMS)衍生物的质谱裂解行为,探讨质谱碎片峰的裂解规律,列出每种化合物的质谱裂解特征,为该化合物的结构确证提供质谱依据。Abstract: Methoxime and TMS derivatives of 4 phytohormones were investigated by gas chromatography time-of-flight mass spectrometry (GC-TOF MS). The fragmentation regularity of these compounds is proposed, and the characteristic fragment ions are pointed out to identify the compounds.