有机磷化合物的质谱研究(XⅢ).1,3,2-二氮磷杂环戊酮-(4)衍生物的电子轰击质谱

  • 摘要: 本文报道9种新的含磷杂环化合物的电子轰击质谱(EIMS),并应用B/E、B2/E联动扫描及精确质量测量技术,探讨了该类化合物的质谱断裂机理,发现骨架重排及开环反应是该类化合物主要的质谱特征,而R2基因对重排过程有很大影响。

     

    Abstract: A Study on Alkali Metal Adduct Ions of Crown Ether Compound in Fast Atom Bombardment Mass SpectrometryLi Haiquan; Chen Nenyu; Chen Tao(National Laboratory of Applied Organic Chemistry, Lanzhou University,Lanzhou 730000, China)Abstract:Fast Atom Bombardment Mass Spectra(FABMS) of four crown ether compounds 1~4 and K+, Na+ forming adducting ions have been studied. For these adducting ions, in their FABMS, M+K+and M+Na+are intense,and may give the information about molecurlar weight exactly.Keywords: crown ether compound,K~+, Na~+,FABMS

     

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