锗丙酰及锗甲基丙酰-α-氨基酸酯系列倍半氧化物的快原子轰击质谱规律研究

  • 摘要: 本文报道了8种新的锗丙酰及锗甲基丙酰-α-氨基酸酯系列倍半氧化物的快原子轰击质谱(FABMS)。结果表明,此类化合物基本不显示分子离子峰.碎片离子的形成以Ge-O键的α-断裂为主要裂解方式,其基峰及主要碎片离子峰均表现出很强的规律性.

     

    Abstract: FABMS of Germanium Propionyl and Methylpropionyl Amino Acid Ester SesquioxidesWu Yiwei; Liu Guoxiang(Department of Chemistry, Capital Normal University, Beijing 100037,China)Hu Wenxiang; Yun Liuhong(Institute of Pharmacology and Toxicology, Academy of Military Medical Sciences,Beijijng 100085, China)Abstract: A series of germanium propionyl and methylpropinoyl amiono acid esters sesquioxides were determined by the fast atomic bombardment mass spectrometry (FABMS).The correlation between fragement peaks were found and some FABMS phenomenawere discussed.Keywords: germanium propionyl and methylpropionyl amino acid ester sesquioxides, fast atomic bombardment, mass spectrometry

     

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