同位素稀释质谱法对年青玄武岩K-Ar年龄的测定

  • 摘要: 用同位素稀释质谱法在RGA-10质谱计和析Ar仪联合系统中,分析测定了一批年青(第四纪)玄武岩样品的常规K-Ar年龄。绝大多数样品的年龄值在0.1~0.7Ma之间,只有少数几个样品的年龄值在1~2Ma之间,所测年龄都在第四纪范围内。部分样品经过重复检测获得了良好的重现性,这表明测量精度和准确度都比较高。经检测样品的大气40Ar/36Ar比值在295.5±5以内。这与当今大气Ar比值295.5无明显差别,证明样品不含过剩40Ar和36Ar,测得的年龄值是真实可信的。大多数样品的测定误差在±5%以内,仅有少数几个样品的测定误差在±5~±10%之间,这样的测试水平对年青的第四纪地质样品而言是完全可以接受的。

     

    Abstract: Determination of K-Ar Ages on Some Young Basalts by IDMSSang Haiqing;Qiu Ji;Wang Songshan;Hu Shiting(Institute of Geology,Chinese Academy ofSciences,Beijing 100029,China)Received Abstract:The present paper reports some results of K-Ar ages in young basalts from northwest and northeast region of China.These results are determined by 38Ar isotope dilutien mass spectrometry(IDMS).The particle size of samples analysed sanes in a range from 0.20 to 0.63 mm in diameter is selected.We use an ultra-high vacuum system for argon extraction and a RGA-10 mass spectrometer operated in static mode for isotopic measurement.The isotopic ratios of argon for spike are40Ar/38Ar=7.4364×10-3,36Ar/38Ar=5.0868×10-5.All argon isotopes has been corrected for memory effect.Using flame photometry the potassium is determined.Finally,we use following contants λe=0.581×10-10/year,λβ=4.962×10-10/year,λ=5.543×10-10/year and 40Ar/K=1.167×10-104(mole/mole)for age calculation.The age range of all basalts is from 0.116 to 2.101 Ma.Also,the standard diviation is given for every measured age.The measurement precision of most samples is within ±5%.The results indicate well for young samples.Keywords:young basalt,K-Ar age,IDMS

     

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