重馏份油族组成质谱分析中的影响因素

  • 摘要: 质谱定量分析方法的重复性一直受到人们的关注,本文对影响重复性的一些仪器条件进行了探讨。结果表明,重复性的好坏,可以通过改变进样量和检测器电压反映出来。测定结果保持稳定时,上述二者的可调范围愈大,重复性愈好。灯丝电流对正十六烷∑69/∑71比值的影响最大,且有规律可循:灯丝电流高时此比值也增大,并有一个合适范围使测定结果稳定。

     

    Abstract: The Effect Factors on the Analysis of Hydrocarbon Types in Heavy Distillates of Petroleum by Mass SpectrometryZhao Tianbao;Lin Minling;Qian Maiyuan;Shi Fang(Fusun Research Institute of Petroleum and Petrochemicals,Fushun 113001,China)Received Abstract:The influence of some conditions of mass spectrometer such as trap current detector voltage and the amount of sample on the accuracy and repeatability of the quantitative analysis are discussed.The results show that the repeatability can be reflected by the effect of sample amount and detector voltage to the result.The larger the adjustable range of the above two with stable results,the better the repeatability is.The effect of the trap current on the∑69/∑71 ratio of normal hexadecane is the most important.The ratio will increase with the trap current and within a certain range which is suitable and stable.Keywords:mass spectrometry,quantitative analysis,heavy distillates of petroleum,hydrocarbon types.

     

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